Home > Uncategorized > Thermodynamics and Kinetics Lecture 32 Notes: Kinetics

Thermodynamics and Kinetics Lecture 32 Notes: Kinetics

Overview
Today’s lecture costs 51 minutes. The front of this class is very empty; the teachers must be chasing the students away. At this stage, it’s a whole lot of mathematical voodoo.

Details
Mechanisms cannot be proved, but they can be disproved. There might be an unmeasurable intermediate.

A=B + C
A=B
A=C
We’re going to do a reaction where A-B is 1st order and A-C is 2nd order. Begin by writing all rate laws.

-dA/dt = k1A + k2A^2
dB/dt = k1A
dC/dt = k1A^2

A falls exponentially, B and C increase to an assymototic limi.
k2A<>ka and early times, k1T<<1

A-B-C
Begin by writing the rate laws
-dA/dt = k1A
dB/dt = k1A-k2B
dC/dt=k2B

C=(Ao-A)-B

e^-kt = 1-kt+(kt)^2/2…Taylor series

Review
oh my such great apple pie: oxalic malonic succinic glutaric adipic paleric.
G=H-TS=-RTlnK=-nFE
Tooth: enamel, dentis, pulp

K=products/reactants
Op Amp
Non Inverting G = Vo/Vi = 1+Rf/Ro
Inverting G = -Rf/Ro

sight alignment, sight picture, trigger control
BRASS breathe relax aim sight shoot
BRASS breathe relax aim slack squeeze
BLISS blend low irregular small secluded
LACE liquid ammo casualties equipment
METTTC mission enemy troops terrain time civilians
SPLC staffing probabilities logistics contingencies

1st Law dU = dQ + dW
2nd Law dS = dQ rev/T
3rd Law OK, s=0

Sensory Layer: fovea, macula, peripheral

Add acid to water, not water to acid

u = G/n
Polymerization: condensation/radical

high pass filter, differentiator
low pass filter, integrator

ACP NRR abduction containment proof of lifenegotiation ransom drop release

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