Home > Uncategorized > Thermodynamics and Kinetics Lecture 36 Notes: Oscillators

Thermodynamics and Kinetics Lecture 36 Notes: Oscillators

Overview
Today is the last lecture of this series. It is only 40 minutes long.

Details
The turnover number is the rate per second. The number of times a reactant turns into a product per second per catalyst.
K = rate of product/moles of enzyme
dP/dt/(Eo) = k max/Eo

Oscillating reactions are interesting. Coupled differential equations.
A B
A + B = 2B
-dA/dt=k A B
B=Bo +2(Ao-A) -(Ao-A)
This leads to an S shaped curve.

Lotka Voltera Mechanism
A + B =2B
B+C = 2C
C=Product
dB/dt = k1AB-k2BC
dC/dt=k2BC-k3C
Assume we are at steady state. Then preturb away from it. Harmonic response.

Review
Man = 20 to 20k
Dog=40-60k
organic layer top, aqueous below
oh my such great apple pie: oxalic malonic succinic glutaric adipic paleric.
G=H-TS=-RTlnK=-nFE
Tooth: enamel, dentis, pulp

a=yc

K=products/reactants
Op Amp
Non Inverting G = Vo/Vi = 1+Rf/Ro
Inverting G = -Rf/Ro

sight alignment, sight picture, trigger control
BRASS breathe relax aim sight shoot
BRASS breathe relax aim slack squeeze
BLISS blend low irregular small secluded
LACE liquid ammo casualties equipment
METTTC mission enemy troops terrain time civilians
SPLC staffing probabilities logistics contingencies

1st Law dU = dQ + dW
2nd Law dS = dQ rev/T
3rd Law OK, s=0

Sensory Layer: fovea, macula, peripheral

Add acid to water, not water to acid

u = G/n
Polymerization: condensation/radical

ACP NRR abduction captivity proof of life, negotiation ransom, recovery

high pass filter, differentiator
low pass filter, integrator

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